|
Advanced oxidation processes (abbreviation: AOPs), in a broad sense, refers to a set of chemical treatment procedures designed to remove organic (and sometimes inorganic) materials in water and waste water by oxidation through reactions with hydroxyl radicals (·OH). In real-world applications of wastewater treatment, however, this term usually refers more specifically to a subset of such chemical processes that employ ozone (O3), hydrogen peroxide (H2O2) and/or UV light. One such type of process is called in situ chemical oxidation. ==Description== AOPs rely on in-situ production of highly reactive hydroxyl radicals (·OH). These reactive species are the strongest oxidants that can be applied in water and can virtually oxidize any compound present in the water matrix, often at a diffusion controlled reaction speed. Consequently, ·OH reacts unselectively once formed and contaminants will be quickly and efficiently fragmented and converted into small inorganic molecules. Hydroxyl radicals are produced with the help of one or more primary oxidants (e.g. ozone, hydrogen peroxide, oxygen) and/or energy sources (e.g. ultraviolet light) or catalysts (e.g. titanium dioxide). Precise, pre-programmed dosages, sequences and combinations of these reagents are applied in order to obtain a maximum •OH yield. In general, when applied in properly tuned conditions, AOPs can reduce the concentration of contaminants from several-hundreds ppm to less than 5 ppb and therefore significantly bring COD and TOC down, which earned it the credit of “water treatment processes of the 21st century”. The AOP procedure is particularly useful for cleaning biologically toxic or non-degradable materials such as aromatics, pesticides, petroleum constituents, and volatile organic compounds in waste water. Additionally, AOPs can be used to treat effluent of secondary treated wastewater which is then called tertiary treatment. The contaminant materials are converted to a large extent into stable inorganic compounds such as water, carbon dioxide and salts, i.e. they undergo mineralization. A goal of the waste water purification by means of AOP procedures is the reduction of the chemical contaminants and the toxicity to such an extent that the cleaned waste water may be reintroduced into receiving streams or, at least, into a conventional sewage treatment. Although oxidation processes involving ·OH have been in use since late 19th century (such as in Fenton reagent, which, however, was an analytical reagent at that time), the utilization of such oxidative species in water treatment did not receive adequate attention until Glaze et al.〔 suggested the possible generation of ·OH “in sufficient quantity to affect water purification” and defined the term “Advanced Oxidation Processes” for the first time in 1987. AOPs still have not been put into commercial use on a large scale (especially in developing countries) even up to today mostly because of the relatively high costs. Nevertheless, its high oxidative capability and efficiency make AOPs a popular technique in tertiary treatment in which the most recalcitrant organic and inorganic contaminants are to be eliminated. The increasing interest in water reuse and more stringent regulations regarding water pollution are currently accelerating the implementation of AOPs at full-scale. There are roughly 500 commercialized AOPs installations around the world at present, mostly in Europe and the United States. Other countries like China are showing increasing interests in AOPs. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Advanced oxidation process」の詳細全文を読む スポンサード リンク
|